STUDENT SPACE · TOPIC 2

Electrode half-equations

Construct balanced oxidation and reduction half-equations.

The essentials

  • A metal ion gains electrons and becomes a neutral atom.
  • Bromide ions lose electrons. Two bromine atoms form one Br₂ molecule.
  • Pb²⁺ + 2e⁻ → Pb has total charge 0 on both sides.

Key vocabulary

EnglishChinese
cation阳离子
anion阴离子
discharge放电
charge balance电荷守恒

Quick practice

Try each question before opening its hint or answer. Use paper for calculations and diagrams.

Question 1

Complete and balance: Al³⁺ + __ → __.

Need a hint for Question 1?

Balance atoms first, then compare total charge and add electrons.

Check Question 1

Al³⁺ + 3e⁻ → Al.

Question 2

Write the cathode half-equation for molten MgCl₂.

Need a hint for Question 2?

Positive magnesium ions gain electrons.

Check Question 2

Mg²⁺ + 2e⁻ → Mg.

Question 3

Write the anode half-equation for molten MgCl₂ and explain whether it is oxidation or reduction.

Need a hint for Question 3?

Balance chlorine atoms and charge; identify electron loss or gain.

Check Question 3

2Cl⁻ → Cl₂ + 2e⁻. Oxidation because chloride ions lose electrons.

Use Lesson 2 in your worksheet for written practice. Your teacher will discuss those answers in class.

Electrolytic cell · a power supply drives change

DC supply−+Molten PbBr₂ · mobile ionsCathode (−)Anode (+)e⁻: supply → cathode; anode → supply+−+−+−Pb²⁺ → cathode; Br⁻ → anodeElectrical energy → chemical change

Electrons carry charge in metal wires. Ions carry charge in the electrolyte.

Predict first: Name both products and write the half-equations. What changes if you change the anode material?

Schematic teaching model: motion and particle numbers are illustrative. Moving anions do not necessarily discharge: electrode material and competing ions determine products.

PREDICT · TRY · EXPLAIN · 3–5 MINUTES

Inside an electrolytic cell

Predict the product at each electrode. Run the cell, then explain where ions and electrons move.

Molten PbBr₂; inert electrodes. This is a model, not a home experiment.

DC power supply
− supplies electrons to cathode · + removes electrons from anode
− Cathode
Reduction
+ Anode
Oxidation
← Pb²⁺ cationsBr⁻ anions →

Electrons travel through wires and electrodes. Ions carry charge through the electrolyte. Movement towards an electrode does not mean an ion must be discharged there.

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