STUDENT SPACE · TOPIC 3

Aqueous solutions

Predict products when water also supplies ions.

The essentials

  • In aqueous NaCl, consider Na⁺, Cl⁻, H⁺ and OH⁻.
  • For these aqueous examples, a metal more reactive than hydrogen stays as ions; hydrogen forms.
  • With inert electrodes, concentrated chloride or bromide solutions give the halogen.

Key vocabulary

EnglishChinese
aqueous水溶液的
concentrated浓的
dilute稀的
inert electrode惰性电极

Quick practice

Try each question before opening its hint or answer. Use paper for calculations and diagrams.

Question 1

Why does aqueous NaCl give hydrogen instead of sodium at the cathode?

Need a hint for Question 1?

List all ions before choosing products. Check whether the question says molten, dilute or concentrated.

Check Question 1

Sodium is more reactive than hydrogen; hydrogen is discharged and Na⁺ remains in solution.

Question 2

Predict both products from concentrated aqueous KBr using inert electrodes.

Need a hint for Question 2?

Include the ions supplied by water as well as the salt.

Check Question 2

Cathode: hydrogen. Anode: bromine.

Question 3

Predict both products from dilute sulfuric acid and give the expected gas volume ratio.

Need a hint for Question 3?

Use the overall decomposition of water to determine the gas ratio.

Check Question 3

Hydrogen at cathode, oxygen at anode; H₂:O₂ = 2:1 at the same conditions.

Use Lesson 3 in your worksheet for written practice. Your teacher will discuss those answers in class.

PREDICT · TRY · EXPLAIN · 3–5 MINUTES

Inside an electrolytic cell

Predict the product at each electrode. Run the cell, then explain where ions and electrons move.

Molten PbBr₂; inert electrodes. This is a model, not a home experiment.

DC power supply
− supplies electrons to cathode · + removes electrons from anode
− Cathode
Reduction
+ Anode
Oxidation
← Pb²⁺ cationsBr⁻ anions →

Electrons travel through wires and electrodes. Ions carry charge through the electrolyte. Movement towards an electrode does not mean an ion must be discharged there.

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