STUDENT SPACE · TOPIC 4

Concentration and titration calculations

Convert concentration units and calculate unknown concentration from titration data.

The essentials

  • Use the final volume of the solution, not the volume of water added.
  • n = cV; V = n/c. Use V in dm³ when c is in mol/dm³.
  • Molar concentration: amount (mol) ÷ solution volume (dm³).
  • Mass concentration: mass (g) ÷ solution volume (dm³).

Key vocabulary

EnglishChinese
concentration浓度
solution volume溶液体积
titration滴定

Quick practice

Try each question before opening its hint or answer. Use paper for calculations and diagrams.

Question 1

Why does the expression 0.100 × 20.0 give the wrong number of moles for 20.0 cm³ solution?

Need a hint for Question 1?

Use the relationships above and check particle ratios and units.

Check Question 1

The volume must be in dm³: use 0.0200, not 20.0.

Question 2

4.0 g NaOH is made up to 250 cm³ solution. Find concentration in g/dm³ and mol/dm³. M = 40 g/mol.

Need a hint for Question 2?

Convert 250 cm³ to dm³; use mass or moles per volume.

Check Question 2

4.0/0.250 = 16 g/dm³; (4.0/40)/0.250 = 0.40 mol/dm³.

Question 3

HCl + NaOH → NaCl + H₂O. Find the volume of 0.100 mol/dm³ NaOH needed for 25.0 cm³ of 0.200 mol/dm³ HCl.

Need a hint for Question 3?

Find acid moles, use the 1:1 ratio and then calculate alkali volume.

Check Question 3

n(HCl) = 0.200 × 0.0250 = 0.00500 mol. V(NaOH) = 0.0500 dm³ = 50.0 cm³.

Use Lesson 4 in your worksheet for written practice. Your teacher will discuss those answers in class.

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